Tetraaquabis(6-carboxy-1H-benzimidazole-5-carboxylato-κN 3)nickel(II) dimethylformamide disolvate dihydrate
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چکیده
The title compound, [Ni(C(9)H(45)N(2)O(4))(2)(H(2)O)(4)]·2C(3)H(7)NO·2H(2)O, has the Ni(II) center coordinated by four water mol-ecules and two N atoms from two 1H-benzimidazole-5,6-dicarboxyl-ate ligands in an octa-hedral geometry. The mol-ecule inter-acts with the solvent water and dimethyl-formamide mol-ecules through N-H⋯O and O-H⋯O hydrogen bonds to form a three-dimensional supra-molecular network. The metal atom lies on a center of inversion.
منابع مشابه
Tetraaquabis(1H-benzimidazole-5,6-dicarboxylato-κN 3)cobalt(II) dimethylformamide disolvate dihydrate
In the mononuclear title compound, [Co(C(9)H(4)N(2)O(4))(2)(H(2)O)(4)]·2C(3)H(7)NO·2H(2)O, the Co(II) atom, which lies on a center of inversion, is coordinated by four water mol-ecules and two N atoms from two two symmetry-related 1H-benzimidazole-5,6-dicarboxyl-ate ligands in a distorted octa-hedral geometry. The packing is governed by inter-molecular O-H⋯O and N-H⋯O hydrogen-bonding inter-act...
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